The
refractive index (or
index of refraction) of a medium is a measure for how much the speed of light (or other waves such as sound waves) is reduced inside the medium. For example, typical
glass has a refractive index of 1.5, which means that light travels at
times the speed in air or vacuum. Two common properties of glass and other transparent materials are directly related to their refractive index. First, light rays change direction when they cross the interface from air to the material, an effect that's used in lenses and
glasses. Second, light reflects partially from surfaces that have a refractive index different from that of their surroundings.
Definition
The refractive index
n of a medium is defined as the ratio of the
phase velocity c of a
wave phenomenon such as
light or
sound in a reference medium to the phase velocity
Here,
n is the refractive index indicating the phase velocity as above, while
κ is called the
extinction coefficient, which indicates the amount of
absorption loss when the electromagnetic wave propagates through the material. Both
n and
κ are dependent on the frequency (
wavelength).
The effect that
n varies with
frequency (except in vacuum, where all frequencies travel at the same speed,
c) is known as
dispersion, and it's what causes a
prism to divide white light into its constituent spectral
colors, explains
rainbows, and is the cause of
chromatic aberration in
lenses. In regions of the spectrum where the material doesn't absorb, the real part of the refractive index tends to increase with frequency. Near absorption peaks, the curve of the refractive index is a complex form given by the
Kramers-Kronig relations, and can decrease with frequency.
Since the refractive index of a material varies with the frequency (and thus wavelength) of light, it's usual to specify the corresponding vacuum wavelength at which the refractive index is measured. Typically, this is done at various well-defined spectral
emission lines; for example,
nD is the refractive index at the
Fraunhofer "D" line, the centre of the yellow
sodium double emission at 589.29
nm wavelength.
The
Sellmeier equation is an empirical formula that works well in describing dispersion, and Sellmeier coefficients are often quoted instead of the refractive index in tables. For some representative refractive indices at different wavelengths, see
list of indices of refraction.
As shown above, dielectric loss and non-zero DC conductivity in materials cause absorption. Good dielectric materials such as glass have extremely low DC conductivity, and at low frequencies the dielectric loss is also negligible, resulting in almost no absorption (κ ≈ 0). However, at higher frequencies (such as visible light), dielectric loss may increase absorption significantly, reducing the material's
transparency to these frequencies.
The real and imaginary parts of the complex refractive index are related through use of the
Kramers-Kronig relations. For example, one can determine a material's full complex refractive index as a function of wavelength from an absorption spectrum of the material.
Anisotropy
The refractive index of certain media may be different depending on the
polarization and direction of propagation of the light through the medium. This is known as
birefringence or anisotropy and is described by the field of
crystal optics. In the most general case, the
dielectric constant is a rank-2
tensor (a 3 by 3 matrix), which can't simply be described by refractive indices except for polarizations along principal axes.
In magneto-optic (gyro-magnetic) and
optically active materials, the principal axes are complex (corresponding to elliptical polarizations), and the dielectric tensor is complex-
Hermitian (for lossless media); such materials break time-reversal symmetry and are used for example to construct
Faraday isolators.
Nonlinearity
The strong
electric field of high intensity light (such as output of a
laser) may cause a medium's refractive index to vary as the light passes through it, giving rise to
nonlinear optics. If the index varies quadratically with the field (linearly with the intensity), it's called the
optical Kerr effect and causes phenomena such as
self-focusing and
self phase modulation. If the index varies linearly with the field (which is only possible in materials that don't possess
inversion symmetry), it's known as the
Pockels effect.
Inhomogeneity
If the refractive index of a medium isn't constant, but varies gradually with position, the material is known as a gradient-index medium and is described by
gradient index optics. Light travelling through such a medium can be bent or focussed, and this effect can be exploited to produce
lenses, some
optical fibers and other devices. Some common
mirages are caused by a spatially-varying refractive index of
air.
Refractive index and density
In general, the refractive index of a glass increases with its density. However, there doesn't exist an overall linear relation between the refractive index and the density for all silicate and borosilicate glasses. A relatively high refractive index and low density can be obtained with glasses containing light metal oxides such as Li2O and MgO, while the opposite trend is observed with glasses containing PbO and BaO as seen in the diagram at the right.
Applications
The refractive index of a material is the most important property of any
optical system that uses
refraction. It is used to calculate the focusing power of lenses, and the dispersive power of prisms.
Since refractive index is a fundamental physical property of a substance, it's often used to identify a particular substance, confirm its purity, or measure its concentration. Refractive index is used to measure solids (glasses and gemstones), liquids, and gases. Most commonly it's used to measure the concentration of a
solute in an
aqueous solution. A
refractometer is the instrument used to measure refractive index. For a solution of sugar, the refractive index can be used to determine the sugar content (see
Brix).
External results
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